McMurry‐Reaktion der 2‐Alkyl‐3‐ethoxyacroleine | Zendy

Dormagen Walter | Zendy; Breitmaier Eberhard | Zendy

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McMurry‐Reaktion der 2‐Alkyl‐3‐ethoxyacroleine

Author(s) -

Dormagen Walter,

Breitmaier Eberhard

Publication year - 1986

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19861190526

Subject(s) - chemistry , alkyl , double bond , coupling (piping) , medicinal chemistry , proton , coupling reaction , photochemistry , polymer chemistry , organic chemistry , catalysis , physics , quantum mechanics , mechanical engineering , engineering

McMurry Reaction of 2‐Alkyl‐3‐ethoxyacroleins McMurry reductive coupling of 2‐alkyl‐3‐ethoxyacroleins 1 yields 2,5‐dialkylhexadienedials 6 . ( E ) Configuration at the 2,3‐ and 4,5‐double bonds of these dialdehydes is derived from three‐bond carbon‐13 proton coupling. A mechanism similiar to that discussed for McMurry coupling of carbonyl compounds is proposed.

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