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Synthesis and twisted intramolecular charge transfer(TICT)‐fluorescence of 8,8′‐bi‐naphtho[1,2,3,4‐ def ]chrysenyl
Author(s) -
Bunte Reinhard,
Gundermann KarlDietrich,
Leitich Johannes,
Polansky Oskar E.,
Zander Maximilian
Publication year - 1986
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19861190519
Subject(s) - chemistry , chrysene , intramolecular force , chlorobenzene , fluorescence , photochemistry , charge (physics) , stereochemistry , anthracene , organic chemistry , physics , quantum mechanics , catalysis
Upon irradiation of naphtho[1,2,3,4‐ def ]chrysene ( 3 ) in chlorobenzene a symmetric biaryl, 8,8′‐bi‐naphtho[1,2,3,4‐ def ]chrysenyl ( 4 ), is formed. Fluorescence studies of 4 reveal that the emission originates from a TICT state.