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Bicyclo[4.1.1]octa‐2,4‐dien‐7‐on
Author(s) -
König Lothar,
Brinker Udo H.
Publication year - 1986
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19861190134
Subject(s) - bicyclic molecule , chemistry , acetal , iodobenzene , ketone , halogenation , stereochemistry , medicinal chemistry , organic chemistry , catalysis
Bicyclo[4.1.1]octa‐2,4‐dien‐7‐one The title compound 1 was prepared in four steps starting from bicyclo[4.1.1]oct‐2‐en‐7‐one ( 2 ). Acetalisation of 2 afforded 3 which was treated with iodobenzene dichloride to give 4 . After dehalogenation and cleavage of the acetal function in 5 ketone 1 is obtained.