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Darstellung von cis ‐Dichloro[tellurobis(di‐ tert ‐butyl‐phosphan)]platin(II)
Author(s) -
Hensel Ralph,
Mont WolfWalther Du
Publication year - 1985
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19851181233
Subject(s) - chemistry , benzonitrile , platinum , toluene , methylene , medicinal chemistry , chelation , chloride , yield (engineering) , stereochemistry , organic chemistry , catalysis , materials science , metallurgy
Preparation of cis ‐Dichloro[tellurobis(di‐ tert ‐butylphosphane)]platinum(II) The title complex 2 is obtained in 50–60% yield from heterogeneous reactions between tellurobis(di‐ tert ‐butylphosphane) ( 1 ) and bis(benzonitrile)dichloroplatinum(II) in methylene chloride or platinum dichloride in toluene suspension. NMR and MS data are consistent with a chelate‐type Cl 2 Pt( t Bu 2 P) 2 Te structure of the new complex.