Thermolabile Hydrocarbons, XXVII. 2,3‐Di‐1‐adamantyl‐2,3‐dimethylbutane; Long Bonds and Low Thermal Stability | Zendy

Meer Manuela A. Flammter | Zendy; Beckhaus HansDieter | Zendy; Peters Karl | Zendy; von Schnering HansGeorg | Zendy; Rüchardt Christoph | Zendy

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Thermolabile Hydrocarbons, XXVII. 2,3‐Di‐1‐adamantyl‐2,3‐dimethylbutane; Long Bonds and Low Thermal Stability

Author(s) -

Meer Manuela A. Flammter,

Beckhaus HansDieter,

Peters Karl,

von Schnering HansGeorg,

Rüchardt Christoph

Publication year - 1985

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19851181203

Subject(s) - chemistry , thermolabile , alkane , stereochemistry , medicinal chemistry , hydrocarbon , organic chemistry , enzyme

The title compound 2 was prepared by a Wurtz procedure. Its highly deformed structure was determined by X ‐ray analysis and matched with high precision by MM 2 force field calculations. The three neighbouring C q C q bonds are longer than 164 pm and the C q C q C q bond angles are 118°. According to MM 2 calculations and a kinetic investigation 2 is the most strained and least stable member of the C q C q alkane series investigated previously 2) .

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