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Beiträge zur Chemie des Phosphors, 154. 1‐ tert ‐Butyl‐2‐methylphosphiran – ein thermisch beständiges Monophosphiran
Author(s) -
Baudler Marianne,
Germeshausen Joachim
Publication year - 1985
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19851181036
Subject(s) - chemistry , propane , liquid ammonia , medicinal chemistry , hexane , ammonia , organic chemistry
Contributions to the Chemistry of Phosphorus, 154. 1‐ tert ‐Butyl‐2‐methylphosphirane – a Thermally Stable Monophosphirane The title compound 1 has been synthesized by [2 + 1]‐cyclocondensation of 1,2‐dichloro‐propane with dilithium tert ‐butylphosphide in liquid ammonia/ n ‐hexane. In spite of the low degree of substitution 1 is a surprisingly stable monophosphirane (phosphacyclopropane).