Notizen. 1‐Methyl‐7‐norbornyliden. Selektive Alkylverschiebung in Carbenen | Zendy

Kirmse Wolfgang | Zendy; Streu Joachim | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Notizen. 1‐Methyl‐7‐norbornyliden. Selektive Alkylverschiebung in Carbenen

Author(s) -

Kirmse Wolfgang,

Streu Joachim

Publication year - 1984

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19841171217

Subject(s) - chemistry , photodissociation , alkyl , thermal decomposition , sodium salt , medicinal chemistry , salt (chemistry) , sodium , stereochemistry , organic chemistry , inorganic chemistry

1‐Methyl‐7‐norbornylidene. Selective Alkyl Shifts of Carbenes 1‐Methyl‐7‐norbornylidene ( 14 ), generated from the sodium salt of the analogous tosylhydrazone ( 7 ), rearranges preferentially with migration of the C‐1–C‐2 (C‐1–C‐6) bond. The ratios of 2‐methyl‐ over 5‐methylbicyclo[3.2.0]heptenes ( 15 + 16:20 ) range from 5 (thermolysis, 290°C to 21 (photolysis, 25°C).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research