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Notizen. Reduktive Substitution der Acetat‐Gruppe in Allyl‐, Propargyl‐ und Benzylacetaten durch NaBH 4 /NiCl 2 · 6 H 2 O
Author(s) -
Ipaktschi Junes
Publication year - 1984
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19841171116
Subject(s) - chemistry , propargyl , medicinal chemistry , propargyl alcohol , steric effects , organic chemistry , catalysis
Reductive Displacement of the Acetate Group in Allyl, Propargyl, and Benzyl Acetates by NaBH 4 /NiCl 2 · 6 H 2 O The combination of NiCl 2 · 6 H 2 O and NaBH 4 provides an effective system for reductive removal of the acetate group of allyl, propargyl, and benzyl acetates. Sterically less hindered allyl acetates are converted preferentially to the corresponding alkanes (Table 1).