Notizen.Bestimmung absoluter Geschwindigkeitskonstanten bei der radikalischen Addition an Alkene nach der “Quecksilbermethode” | Zendy

Giese Bernd | Zendy; Kretzschmar Gerhard | Zendy

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Notizen.Bestimmung absoluter Geschwindigkeitskonstanten bei der radikalischen Addition an Alkene nach der “Quecksilbermethode”

Author(s) -

Giese Bernd,

Kretzschmar Gerhard

Publication year - 1984

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19841171015

Subject(s) - chemistry , acrylonitrile , alkene , reaction rate constant , radical , methyl acrylate , medicinal chemistry , photochemistry , mercury (programming language) , polymer chemistry , organic chemistry , kinetics , catalysis , polymer , physics , quantum mechanics , computer science , copolymer , programming language

Measurement of Absolute Rates of Radical Additions to Alkenes by the “Mercury Method” Using the 5‐hexenyl radical ( 2 ) as “radical clock” the rates of radical additions to methyl acrylate ( 5a ) and acrylonitrile ( 5b ) are measured by the “mercury method” (Table 1). Alkyl radicals are trapped by the alkylmercury hydride 1 with rate constants of at least 10 7 1 · mol −1 · s −1 .

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