Übergangsmetallketen‐Verbindungen, XXII. Anionische η 2 ‐Ketenylkomplexe von Molybdän und Wolfram | Zendy

Kreißl Fritz R. | Zendy; Sieber Werner J. | Zendy; Alt Helmut G. | Zendy

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Übergangsmetallketen‐Verbindungen, XXII. Anionische η 2 ‐Ketenylkomplexe von Molybdän und Wolfram

Author(s) -

Kreißl Fritz R.,

Sieber Werner J.,

Alt Helmut G.

Publication year - 1984

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19841170724

Subject(s) - chemistry , molybdenum , carbyne , tungsten , cyclopentadienyl complex , transition metal , medicinal chemistry , tungsten compounds , ketene , ligand (biochemistry) , metal , stereochemistry , inorganic chemistry , carbene , organic chemistry , catalysis , biochemistry , receptor

Transition Metal Ketene Compounds, XXII. Anionic η 2 ‐Ketenyl Complexes of Molybdenum and Tungsten Anionic η 2 ‐ketenyl complexes [NR 4 ′]{η 5 ‐C 5 H 5 (CO) (CN)M[η 2 ‐OCCR]} [M = molybdenum: 3a, b ; M = tungsten: 4a – c ] are formed by ligand substitution on neutral η 2 ‐ketenyl compounds as well as by reaction of dicarbonyl(η 5 ‐cyclopentadienyl)carbyne complexes with tetraalkylammonium cyanides.

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