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Notizen. Eine reduktive Michaelis‐Becker ‐Reaktion: Darstellung und Eigenschaften des (Pentachlorphenyl)phosphonigsäure‐diethylesters
Author(s) -
Boenigk Winfried,
Hägele Gerhard
Publication year - 1984
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19841170620
Subject(s) - chemistry , redox , medicinal chemistry , organic chemistry , hexachlorobenzene , pollutant
A Reductive Michaelis‐Becker Reaction: Synthesis and Properties of Diethyl (Pentachlorophenyl)phosphonite Hexachlorobenzene ( 1 ) reacts with sodium diethyl phosphite ( 3 ) to form diethyl (pentachlorophenyl)phosphonite ( 6 ) in a novel heterogeneous redox reaction. Subsequent reactions and NMR data are reported.