Fluorierungen von Adamantanderivaten mit Sauerstoffdifluorid

Fluorination of Adamantane Derivatives with Oxygen Difluoride Fluorination of adamantane and adamantane derivatives 1 with OF 2 in the absence of an HF‐trap gives fluoroadamantanes 2 and adamantanols 3 in varying amounts. Increasing yields of 2 are obtained in the presence of Na 2 CO 3 as an HF‐trap. In addition, the fluorooxahomoadamantanes 4b and e are formed in this reaction. The fluorination of adamantanone ( 5 ) with OF 2 leads to analogous products.