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Fluorierungen von Adamantanderivaten mit Sauerstoffdifluorid
Author(s) -
Bolte Gerd,
Haas Alois
Publication year - 1984
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19841170529
Subject(s) - adamantane , chemistry , difluoride , xenon difluoride , medicinal chemistry , organic chemistry , stereochemistry
Fluorination of Adamantane Derivatives with Oxygen Difluoride Fluorination of adamantane and adamantane derivatives 1 with OF 2 in the absence of an HF‐trap gives fluoroadamantanes 2 and adamantanols 3 in varying amounts. Increasing yields of 2 are obtained in the presence of Na 2 CO 3 as an HF‐trap. In addition, the fluorooxahomoadamantanes 4b and e are formed in this reaction. The fluorination of adamantanone ( 5 ) with OF 2 leads to analogous products.