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Thermische [2, 1, 3]‐Eliminierung von Methanthiol aus einem 1,5‐Benzothiazepin‐Derivat
Author(s) -
Kaupp Gerd
Publication year - 1984
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19841170433
Subject(s) - chemistry , methanethiol , derivative (finance) , benzothiazole , photodissociation , stereochemistry , medicinal chemistry , photochemistry , organic chemistry , sulfur , financial economics , economics
Thermal [2,1,3]‐Elimination on Methanethiol from a 1,5‐Benzothiazepine Derivative Upon heating to 200°C, the 1,5‐benzothiazepine derivative 1 eliminates methanethiol to form the benzothiazole derivative 2 , but not the 1,5‐benzothiazepine 5 . The structure of 2 , is established by independent synthesis from 3 , photolysis to give 4 , spectroscopic data. The reaction of 1 , to give 2 and methanethiol is termed a [2,1,3]‐elimination.
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