Phosphonium‐metallate, V. Carbonyl(hydrido)(η 5 ‐pentamethylcyclopentadienyl) (trimethyl‐phosphan)eisen(II): Darstellung und Umsetzung mit Trimethyl(methylen)phosphoran | Zendy

Angerer Winfried | Zendy; Fiederling Klaus | Zendy; Grötsch Georg | Zendy; Malisch Wolfgang | Zendy

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Phosphonium‐metallate, V. Carbonyl(hydrido)(η 5 ‐pentamethylcyclopentadienyl) (trimethyl‐phosphan)eisen(II): Darstellung und Umsetzung mit Trimethyl(methylen)phosphoran

Author(s) -

Angerer Winfried,

Fiederling Klaus,

Grötsch Georg,

Malisch Wolfgang

Publication year - 1983

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19831161217

Subject(s) - chemistry , phosphonium , phosphorane , medicinal chemistry , ylide , methylene , hydride , acetic acid , trimethyl phosphite , organic chemistry , hydrogen

Phosphonium Metalates, V. Carbonyl(hydrido)(η 5 ‐pentamethylcyclopentadienyl)(trimethylphosphane)iron(II): Preparation and Reaction with Trimethyl(methylene)phosphorane The iron hydride C 5 Me 5 (CO) 2 FeH ( 2 ) is obtained by the reaction of Na[Fe(CO) 2 C 5 Me 5 ] ( 1 ) with acetic acid. 2 is converted in the presence of trimethylphosphane to C 5 Me 5 (CO)(Me 3 P)FeH ( 3 ), which reacts with the ylide Me 3 P=CH 2 to give C 5 Me 5 (CO)(Me 3 P)FeMe( 4 ) and Me 3 P via the intermediate formation of the phosphonium salt Me 4 P[Fe(CO)(Me 3 P)C 5 Me 5 ] ( 5 ).

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