Premium
Neuartige Bildung einer Azoverbindung mit dem C‐Gerüst eines Secopentaprismans
Author(s) -
Askani Rainer,
Schneider Wilfried
Publication year - 1983
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19831160625
Subject(s) - chemistry , tetrazine , bicyclic molecule , hydrolysis , stereochemistry , organic chemistry
New Kind of Formation of an Azo Compound with a Secopentaprismane C‐Skeleton Decarboxylating hydrolysis of 5a , which is generated by the reaction of 4 with tetrazine 2 , followed by oxidation yields the hexacyclic azo compound 7a . Thermal denitrogenation of 7a leads to azo compound 14 , while irridiation of both 7a and 14a yields the hexacyclic compound 15 , which could not be transformed into the pentaprismane 16 .
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom