Bis[bis(pentafluor‐λ 6 ‐sulfanyl)amino]quecksilber, Hg[N(SF 5 ) 2 ] 2 | Zendy

Waterfeld Alfred | Zendy; Mews Rüdiger | Zendy

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Bis[bis(pentafluor‐λ 6 ‐sulfanyl)amino]quecksilber, Hg[N(SF 5 ) 2 ] 2

Author(s) -

Waterfeld Alfred,

Mews Rüdiger

Publication year - 1983

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19831160442

Subject(s) - chemistry , sulfanyl , yield (engineering) , mercury (programming language) , medicinal chemistry , sulfur , fluorine , stereochemistry , organic chemistry , materials science , computer science , metallurgy , programming language

Bis[bis(pentafluoro‐λ 6 ‐sulfanyl)amino]mercury, Hg[N(SF 5 ) 2 ] 2 From the neat reaction of SF 5 NSF 4 ( 1 ) and HgF 2 at 20–60°C Hg[N(SF 5 ) 2 ] 2 ( 8 ) was obtained in 50% yield. By 8 transfer of the bis(pentafluoro‐λ 6 ‐sulfanyl)amino group is possible, from CH 3 I and CF 3 )SCl CH 3 N(SF 5 ) 2 ( 11 ) and CF 3 SN(SF 5 ) 2 ( 12 ) were synthesized. A short comparison of the (SF 5 ) 2 N with the (CF 3 ) 2 N group is given.

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