Basische Metalle, XXXIX. Oxidative Additionsreaktionen von HCl und CF 3 CO 2 H an Phosphanpalladium(0)‐Komplexe | Zendy

Werner Helmut | Zendy; Bertleff Werner | Zendy

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Basische Metalle, XXXIX. Oxidative Additionsreaktionen von HCl und CF 3 CO 2 H an Phosphanpalladium(0)‐Komplexe

Author(s) -

Werner Helmut,

Bertleff Werner

Publication year - 1983

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19831160239

Subject(s) - chemistry , oxidative addition , medicinal chemistry , bromide , oxidative phosphorylation , stereochemistry , catalysis , inorganic chemistry , organic chemistry , biochemistry

Basic Metals, XXXIX. Oxidative Addition Reactions of HCI and CF 3 CO 2 H to Phosphanepalladium(0) Complexes Pd(PMe 3 ) 4 , Pd(PMePh 2 ) 4 , and Pd(P i Pr 3 ) 3 react with HCl at low temperatures to form trans ‐[PR 3 ) 2 PdHCl] ( 1 – 3 ). The corresponding complex trans ‐[(P i Pr 3 ) 2 PdH(OCOCF 3 )] ( 4 ) is obtained from Pd(P i Pr 3 ) 3 and CF 3 CO 2 H. The reactions of Pd(PMe 3 ) 4 and Pd(PPh 3 ) 4 with benzyl bromide lead to trans ‐[(PR 3 ) 2 Pd(CH 2 Ph)Br] ( 7 , 8 ).

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