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Thermisch instabile Allene, XII. (1,3,3‐Trichlor‐1,2‐propadienyl)benzol
Author(s) -
Roedig Alfred,
Detzer Norbert
Publication year - 1982
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19821150630
Subject(s) - allene , chemistry , benzene , ketone , medicinal chemistry , organic chemistry , catalysis
Thermally Unstable Allenes, XII. (1,3,3‐Trichloro‐1,2‐propadienyl)benzene The thermally unstable allene 4 is prepared from the ketone 1 via the intermediates 2 and 3 . It dimerizes at room temperature to 5 , whose structure is proven by permanganate degradation.