Niederkoordinierte Phosphor‐Verbindungen, 10. Synthese eines 1,3‐Azaphosphetidins mit exocyclischer (PC)‐Doppelbindung | Zendy

Appel Rolf | Zendy; Halstenberg Mechthild | Zendy; Knoch Falk | Zendy; Kunze Holger | Zendy

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Niederkoordinierte Phosphor‐Verbindungen, 10. Synthese eines 1,3‐Azaphosphetidins mit exocyclischer (PC)‐Doppelbindung

Author(s) -

Appel Rolf,

Halstenberg Mechthild,

Knoch Falk,

Kunze Holger

Publication year - 1982

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19821150629

Subject(s) - chemistry , trimethylsilyl , double bond , silylation , stereochemistry , phosphorus , medicinal chemistry , condensation , organic chemistry , catalysis , physics , thermodynamics

Low‐Coordinated Phosphorus Compounds, 10. Synthesis of a 1,3‐Azaphosphetidine with Exocyclic (PC) Double Bond Interaction of phenylbis(trimethylsilyl)phosphane ( 1 ) with benzoylisocyanide dichloride ( 2 ) yields via halosilane condensation primarily the (phosphinomethylene)phosphane 3 , which gives under cyclisation and (P → O) migration of silyl the isomeric 1,3‐azaphosphetidine 4 , (X‐ray datas).

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