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Thermische Dehydrierung von 1‐Sila‐2,5‐cyclohexadien zu Silabenzol
Author(s) -
Maier Günther,
Mihm Gerhard,
Reisenauer Hans Peter
Publication year - 1982
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19821150243
Subject(s) - chemistry , dehydrogenation , matrix isolation , flash vacuum pyrolysis , pyrolysis , medicinal chemistry , conjugated system , argon , organic chemistry , catalysis , polymer
Thermal Dehydrogenation of 1‐Sila‐2,5‐cyclohexadiene to Silabenzene Flash pyrolysis of 1‐sila‐2,5‐cyclohexadiene ( 1 ) yields silabenzene ( 2 ), which can be identified spectroscopically using matrix isolation in argon at 10 K. On the contrary the isomeric conjugated 1‐sila‐2,4‐cyclohexadiene ( 3 ) forms under identical conditions only traces of silabenzene.