Über Metallalkyl‐ und ‐aryl‐ Verbindungen, XXVII. Darstellung und Kristallstruktur von Bis(phenylethinyl)bis‐( N , N , N ′, N ′‐tetramethylethylendiamin)magnesium, Mg(CCPh) 2 (tmeda) 2 | Zendy

Schubert Bernd | Zendy; Behrens Ulrich | Zendy; Weiss Erwin | Zendy

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Über Metallalkyl‐ und ‐aryl‐ Verbindungen, XXVII. Darstellung und Kristallstruktur von Bis(phenylethinyl)bis‐( N , N , N ′, N ′‐tetramethylethylendiamin)magnesium, Mg(CCPh) 2 (tmeda) 2

Author(s) -

Schubert Bernd,

Behrens Ulrich,

Weiss Erwin

Publication year - 1981

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19811140726

Subject(s) - chemistry , tetramethylethylenediamine , orthorhombic crystal system , crystal structure , aryl , magnesium , octahedron , medicinal chemistry , alkyl , crystallography , metal , stereochemistry , organic chemistry

Metal Alkyl and Aryl Compounds, XXVII. Preparation and Crystal structure of Bis(phenylethynyl)bis( N , N , N ′, N ′‐tetramethylethylenediamine)magnesium, Mg(CCPh) 2 (tmeda) 2 The title compound has been prepared from bis(phenylethynyl)magnesium and N , N , N ′, N ′‐tetramethylethylenediamine (tmeda) and investigated by X ‐ray diffraction methods (orthorhombic space group Cmcm , Z = 4 , 696 (reflections, R = 0.049). It represents a first example of an organomagnesium compound with octahedral coordination of the central atom. The phenylethynyl ligands are in trans position.

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