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Zur Umsetzung des Tricarbonyl(η 4 ‐6,6‐diphenylpentafulven)eisens mit Nucleophilen
Author(s) -
Eilbracht Peter,
Henkes Erhard
Publication year - 1981
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19811140435
Subject(s) - chemistry , nucleophile , methoxide , cyclopentadiene , medicinal chemistry , ligand (biochemistry) , methanol , carbon monoxide , catalysis , organic chemistry , receptor , biochemistry
Conversion of Tricarbonyl(η 4 ‐6,6‐diphenylpentafulvene)iron with Nucleophiles Tricarbonyl(η 4 ‐6,6‐diphenylpentafulvene)iron ( 2a ), reacts with methanol/methoxide to form the “metalloester” 7a via nucleophilic attack of the carbon monoxide ligand. This is contrary to an earlier report in which a bridged cyclopentadiene system 6 has been proposed as reaction product.
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