Premium
Tosylgruppenübertragung mit O , O ′‐Ditosylethylenglycol
Author(s) -
Weber Edwin
Publication year - 1981
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19811140433
Subject(s) - tosyl , chemistry , reagent , yield (engineering) , group (periodic table) , medicinal chemistry , organic chemistry , materials science , metallurgy
Tosyl Group Transfer with O , O ′‐Ditosylethyleneglycol The ability of O , O ′‐ditosylethyleneglycol ( 2a ) to act as tosyl group transfer reagent to neopentyl type alcohols is described. Starting form 1a the spirooxetane 3 can be synthesized via tosyl group transfer in high yield. 4a by double tosyl transfer yields the ditosylate 4b . The homologous ditosylpropyleneglycol 2b does not react in a similar manner.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom