Doppel‐Ionophor mit Dihydrotetraaza[14]annulen‐ und Kronenether‐Funktion | Zendy

Kruse Rolf | Zendy; Breitmaier Eberhard | Zendy

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Doppel‐Ionophor mit Dihydrotetraaza[14]annulen‐ und Kronenether‐Funktion

Author(s) -

Kruse Rolf,

Breitmaier Eberhard

Publication year - 1981

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19811140246

Subject(s) - chemistry , ionophore , annulene , stereochemistry , ligand (biochemistry) , medicinal chemistry , cobalt , chelation , diamine , inorganic chemistry , polymer chemistry , calcium , receptor , organic chemistry , biochemistry

Double‐Ionophore with Dihydrotetraaza[14]annulene‐ and Crownether‐Function Benzo[15]crown‐5 ( 1 ) was converted in four steps into the 4‐amino‐5‐nitro‐derivative 5 , which, after reduction to the diamine 6 , cyclocondenses with 3‐ethoxy‐2‐isopropylacrolein. The resulting trimacrocyclic ligand 7 chelates nickel(II) and cobalt(II) ions and, additionally, potassium and sodium ions, thus being a double ionophore.

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