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3‐Aryl‐3‐chlor‐1,2‐diaziridine als isolierbare Zwischenprodukte bei der Darstellung von 3‐Aryl‐3‐chlor‐3 H ‐1,2‐diazirinen
Author(s) -
Berneth Horst,
Hünig Siegfried
Publication year - 1980
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19801130541
Subject(s) - chemistry , aryl , medicinal chemistry , organic chemistry , alkyl
3‐Aryl‐3‐chloro‐1,2‐diaziridines as Isolable Intermediates in the Preparation of 3‐Aryl‐3‐chloro‐3 H ‐1,2‐diazirines The formation of 3‐aryl‐3‐chloro‐3 H ‐1,2‐diazirines 3 from arylamidines 1 with sodium hypo‐chlorite passes through intermediate 3‐aryl‐3‐chloro‐1,2‐diaziridines 2 , which are isolable at low temperature. The direct path 1 → 3 so far suggested therefore becomes unlikely.