The structures of S 4 N       5    ⊖    , S 4 N       5    ⊕    , and S 5 N 6 . A rationalization based upon molecular orbital theory | Zendy

Bartetzko Richard | Zendy; Gleiter Rolf | Zendy

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The structures of S 4 N 5 ⊖ , S 4 N 5 ⊕ , and S 5 N 6 . A rationalization based upon molecular orbital theory

Author(s) -

Bartetzko Richard,

Gleiter Rolf

Publication year - 1980

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19801130334

Subject(s) - chemistry , rationalization (economics) , molecular orbital , degenerate energy levels , molecular orbital theory , physics , molecule , quantum mechanics , philosophy , epistemology , organic chemistry

Using qualitative arguments from molecular orbital theory the essential features of the structures of S 4 N 5 ⊖ , S 4 N 5 ⊕ , and S 5 N 6 can be rationalized. Possible degenerate rearrangements of all three species are discussed. An extension of the presented model allows also the understanding of the structures of As 4 S 5 and β‐P 4 S 5 .

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