Photochemie aromatischer Nitroverbindungen, XV. Photo‐Vergilbung von Ambrette‐Moschus (4‐ tert ‐Butyl‐3‐methoxy‐2,6‐dinitrotoluol) in methanolischer Alkalilauge | Zendy

Döpp Dietrich | Zendy; ArfstenRomberg Ursula | Zendy; Bolz Waltraut | Zendy; Van Hoof Winfried | Zendy; Kosfeld Helmut | Zendy

Premium

Photochemie aromatischer Nitroverbindungen, XV. Photo‐Vergilbung von Ambrette‐Moschus (4‐ tert ‐Butyl‐3‐methoxy‐2,6‐dinitrotoluol) in methanolischer Alkalilauge

Author(s) -

Döpp Dietrich,

ArfstenRomberg Ursula,

Bolz Waltraut,

Van Hoof Winfried,

Kosfeld Helmut

Publication year - 1979

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19791121220

Subject(s) - chemistry , sodium hydroxide , photodissociation , photochemistry , medicinal chemistry , organic chemistry

Photochemistry of Aromatic Nitro Compounds, XV. Photo‐yellowing of Musk Ambrette (4‐ tert ‐Butyl‐3‐methoxy‐2,6‐dinitrotoluene) in Methanolic Sodium Hydroxide Solution Photolysis (λ ≥ 280 nm) of musk ambrette ( 1 ) in 0.1 N methanolic sodium hydroxide solution gives rise ( via photoreduction) to the corresponding azoxybenzene 2 , which undergoes secondary photolysis to the hydroxyazobenzene 5 , and to the by‐products 3 and 4 via intramolecular photo‐cyclizations.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research