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Metallcarbonyl‐Synthesen, III. Eine ergiebige Hochdrucksynthese von Tetracarbonyl(η 5 ‐cyclopentadienyl)niob, (η 5 ‐C 5 H 5 )Nb(CO) 4
Author(s) -
Herrmann Wolfgang A.,
Biersack Helmut
Publication year - 1979
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19791121219
Subject(s) - cyclopentadienyl complex , chemistry , niobium , carbonylation , medicinal chemistry , inorganic chemistry , catalysis , organic chemistry , carbon monoxide
Syntheses of Metalcarbonyls, III. A Productive High‐Pressure Synthesis of Tetracarbonyl(η 5 ‐cyclopentadienyl)niobium, (η 5 ‐C 5 H 5 )Nb(CO) 4 Tetracarbonyl(η 5 ‐cyclopentadienyl)niobium ( 1 ), which could hitherto be prepared only in small amounts, can be synthesized with reproducible yields by reductive high‐pressure carbonylation of (η 5 ‐C 5 H 5 ) 2 NbCl 2 ( 2 ) on a 5 – 20 g scale.