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Notizen. Synthese und Eigenschaften von Lithium‐tetrakis(trimethylsilyl)aluminat‐Komplexen
Author(s) -
Rösch Lutz,
Altnau Gerald
Publication year - 1979
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19791121217
Subject(s) - chemistry , trimethylsilyl , aluminate , dimethoxyethane , ether , adduct , lithium amide , lithium (medication) , diethyl ether , polymer chemistry , medicinal chemistry , organic chemistry , inorganic chemistry , catalysis , medicine , archaeology , electrode , endocrinology , cement , electrolyte , history , enantioselective synthesis
Synthesis and Properties of Lithium Tetrakis(trimethylsilyl)aluminate Complexes Chlorotrimethylsilane reacts with aluminium and lithium in ether in the presence of mercury to form lithium tetrakis(trimethylsilyl)aluminate, coordinated with diethyl ether, tetrahydrofurane, or dimethoxyethane. Unsolvated lithium tetrakis(trimethylsilyl)aluminate results by repeated sublimation of the ether adduct. The IR, Raman, and NMR spectra are discussed.