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Eine einfache Darstellung der binären Metall‐Schwefel‐Cluster [Mo 3 S 13 ] 2− und [Mo 2 S 12 ] 2− aus MoO 4 2− in praktisch quantitativer Ausbeute
Author(s) -
Müller Achim,
Bhattacharyya Ram Gopal,
Pfefferkorn Bernhard
Publication year - 1979
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19791120240
Subject(s) - chemistry , aqueous solution , yield (engineering) , sulfur , organic chemistry , physics , thermodynamics
Simple Preparation of the Binary Metal‐Sulfur Clusters [MO 3 S 13 ] 2− and [Mo 2 S I2 ] 2− from MoO 4 2− in Practically Quantitative Yield (NH 4 ) 2 [Mo 3 S(S 2 ) 6 ] 2 H 2 O ( 2 ) could be isolated by heating an aqueous solution of MoO 4 2− with (NH 4 2− S x , for several hours. The anions of both compounds are in equilibrium under the stated conditions.