Das He(I)‐Photoelektronenspektrum von 1,2,6,7‐Cyclodecatetraen. Hinweis auf eine starke transannulare Wechselwirkung | Zendy

Böhm Michael C. | Zendy; Gleiter Rolf | Zendy

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Das He(I)‐Photoelektronenspektrum von 1,2,6,7‐Cyclodecatetraen. Hinweis auf eine starke transannulare Wechselwirkung

Author(s) -

Böhm Michael C.,

Gleiter Rolf

Publication year - 1978

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19781111028

Subject(s) - mindo , chemistry , photoemission spectroscopy , x ray photoelectron spectroscopy , physics , nuclear magnetic resonance , molecule , organic chemistry

The He(I) Photoelectron Spectrum of 1,2,6,7‐Cyclodecatetraene. Evidence for a Strong Transannular Interaction The photoelectron spectrum (He(I)) of 1,2,6,7‐cyclodecatetraene ( 3 ) is discussed. The first four bands in the PE spectrum of 3 are assigned by comparison with calculated orbital energies according to MINDO/3. The interaction between both allenic units can be described by the interaction parameters β = −0.58 eV and β′ = −0.07 eV.

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