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Das He(I)‐Photoelektronenspektrum von 1,2,6,7‐Cyclodecatetraen. Hinweis auf eine starke transannulare Wechselwirkung
Author(s) -
Böhm Michael C.,
Gleiter Rolf
Publication year - 1978
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19781111028
Subject(s) - mindo , chemistry , photoemission spectroscopy , x ray photoelectron spectroscopy , physics , nuclear magnetic resonance , molecule , organic chemistry
The He(I) Photoelectron Spectrum of 1,2,6,7‐Cyclodecatetraene. Evidence for a Strong Transannular Interaction The photoelectron spectrum (He(I)) of 1,2,6,7‐cyclodecatetraene ( 3 ) is discussed. The first four bands in the PE spectrum of 3 are assigned by comparison with calculated orbital energies according to MINDO/3. The interaction between both allenic units can be described by the interaction parameters β = −0.58 eV and β′ = −0.07 eV.