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Tetracyclo[4.4.1.0 2,5 .0 7,10 ]undeca‐3,8‐diene Synthese durch Wagner‐Meerwein‐Umlagerung mit anchimer unterstützter Heterolyse
Author(s) -
Martin HansDieter,
Hekman Mirko
Publication year - 1978
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19781110830
Subject(s) - chemistry , heterolysis , diene , stereochemistry , medicinal chemistry , organic chemistry , catalysis , natural rubber
Tetracyclo[4.4.1.0 2,5 .0 7,10 ]undeca‐3,8‐dienes. Synthesis by Wagner‐Meerwein Rearrangement with Anchimerically Assisted Heterolysis The highly strained central σ‐bond in pterodactyladienes is prone to a Wagner‐Meerwein rearrangement with virtually concomitant 1,2‐shift of the leaving group, thereby offering an easy access to tetracyclo[4.4.1.0 2,5 .0 7,10 ]undeca‐3,8‐dienes.
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