Übergangsmetall‐Fulven‐Komplexe, XII. Über (Azulen)tricarbonylchrom(0)‐Komplexe | Zendy

Edelmann Frank | Zendy; Behrens Ulrich | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Übergangsmetall‐Fulven‐Komplexe, XII. Über (Azulen)tricarbonylchrom(0)‐Komplexe

Author(s) -

Edelmann Frank,

Behrens Ulrich

Publication year - 1978

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19781110829

Subject(s) - chemistry , azulene , fulvene , medicinal chemistry , chromium , nucleophile , ring (chemistry) , bicyclic molecule , stereochemistry , photochemistry , organic chemistry , catalysis

Transition Metal Fulvene Complexes, XII. (Azulene)tricarbonylchromium(0) Complexes The synthesis of (azulene)tricarbonylchromium(0) ( 2 ) and tricarbonyl(4,6,8‐trimethylazulene)‐chromium(0) ( 3 ), the first azulene derivatives of hexacarbonylchromium, is described. The Cr(CO) 3 group is coordinated to the five‐membered ring of the azulene. Nucleophilic addition of CH 3 Li to 3 leads to the tricarbonyl(1,7 – 10‐η‐2,4,6,6‐tetramethylbicyclo[5.3.0]deca‐2,4,7,9‐tetraen‐1‐yl)‐chromate anion as salt 4 .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research