Darstellung eines Halbylids  via  Übergangsmetallkomplex | Zendy

Kreißl Fritz R. | Zendy; Eberl Karl | Zendy; Kleine Willi | Zendy

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Darstellung eines Halbylids via Übergangsmetallkomplex

Author(s) -

Kreißl Fritz R.,

Eberl Karl,

Kleine Willi

Publication year - 1978

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19781110641

Subject(s) - carbyne , chemistry , trimethylphosphine , ylide , cationic polymerization , transition metal , cleavage (geology) , bond cleavage , metal , stereochemistry , medicinal chemistry , crystallography , polymer chemistry , organic chemistry , carbene , catalysis , crystal structure , fracture (geology) , geotechnical engineering , engineering

Synthesis of a Half Ylide ria Transition Metal Complex A novel cationic half ylide [Ft 2 NC(PMe 3 ) 2 ][BF 4 ] can be obtained by reaction of trimethylphosphine with the cationic carbyne complex [(CO) 5 CrCNEt 2 ][BF 4 ] followed by cleavage of the metal carbon σ‐bond. A mechanism is proposed which suits the experimental facts.

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