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1,2,7‐Azadiphosphepine — neue Phosphor und Stickstoff enthaltende Heterocyclen
Author(s) -
Zeiß Werner,
Henjes Herbert
Publication year - 1978
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19781110448
Subject(s) - chemistry , bicyclic molecule , ring (chemistry) , medicinal chemistry , phosphor , stereochemistry , organic chemistry , physics , optoelectronics
1,2,7‐Azadiphosphepines — New Phosphorus and Nitrogen Containing Heterocycles 1 reacts with 2 moles of 2 to give the bicyclic compound 3 containing the new 1,2,7‐azadiphosphepine ring system. Diphosphinoamines 5 can be considered as three‐membered segments of the eight‐membered ring system 1 . Thus the amines 5 react with 2 likewise to give monocyclic 1,2,7‐azadiphosphepines 6 .