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Solanum ‐Alkaloide, XLI. Darstellung von (22 R :25 S )‐22.26‐Imino‐5α‐cholestanol‐(3β) aus Dihydrotomatidin B
Author(s) -
Schreiber Klaus,
Adam Günter
Publication year - 1964
Publication title -
chemische berichte
Language(s) - German
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19640970834
Subject(s) - chemistry , cholestanol , stereochemistry , medicinal chemistry , sterol , biochemistry , cholesterol
Das aus Dihydrotomatidin B[(22 R :25 S )‐22.26‐Imino‐5α‐cholestandiol‐(3β.16β)] erhältliche (22 R :25 S )‐3β‐Hydroxy‐22.26‐acetimino‐5α‐cholestanon‐(16) (I) wird unter den Bedingungen der HUANG‐MINLON‐Reduktion in (22 R : 25 S )‐22.26‐Imino‐5α‐cholestanol‐(3β) (IIa) übergeführt. Als Nebenprodukt entsteht das Solanum ‐Steroidalkaloid Demissidin (III).

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