Aminolyse von 2,5‐Bis(aryloxy)‐3,3aγ 4 ,4‐trithia‐1,6‐diazapentalenen — ein Zugang zu makrocyclischen Heteropentalenen | Zendy

Tittelbach Franz | Zendy; Lutze Gerhard | Zendy; Graubaum Heinz | Zendy

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Aminolyse von 2,5‐Bis(aryloxy)‐3,3aγ 4 ,4‐trithia‐1,6‐diazapentalenen — ein Zugang zu makrocyclischen Heteropentalenen

Author(s) -

Tittelbach Franz,

Lutze Gerhard,

Graubaum Heinz

Publication year - 1994

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.1491271120

Subject(s) - aminolysis , chemistry , medicinal chemistry , organic chemistry , catalysis

Aminolysis of 2,5‐Bis(aryloxy)‐3,3aγ 4 ,4‐trithia‐1,6‐diazapentalenes ‐ an Entry to Macrocyclic Heteropentalenes The N,N ′‐bis(3,3aγ 4 ‐trithia‐1,6‐diazapentalenyl)diamines 6, 7 and azacrown ethers 8 , incorporating two sulfur‐containing diazapentalenes, have been synthesized from 2,5‐bis(aryloxy)‐3,3aγ 4 ,4‐trithia‐1,6‐diazapentalenes 1 and diamines. The aminolysis of 1 with amines has also been studied providing 2‐monoamino‐ 3 and 2,5‐diaminoheteropentalenes 4.

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