Übergangsmetall‐Silyl‐Komplexe, 5211 [1] . Bildung von Kupfer‐Silyl‐ und ‐Stannyl‐Komplexen durch Umsetzung von [Ph 3 PCuH] 6  mit HER 3  (E = Si, Sn) | Zendy

Schubert Ulrich | Zendy; Mayer Brigitte | Zendy; Ruß Claudia | Zendy

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Übergangsmetall‐Silyl‐Komplexe, 5211 [1] . Bildung von Kupfer‐Silyl‐ und ‐Stannyl‐Komplexen durch Umsetzung von [Ph 3 PCuH] 6 mit HER 3 (E = Si, Sn)

Author(s) -

Schubert Ulrich,

Mayer Brigitte,

Ruß Claudia

Publication year - 1994

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.1491271117

Subject(s) - chemistry , silylation , copper , transition metal , medicinal chemistry , stereochemistry , catalysis , organic chemistry

Transition Metal Silyl Complexes, 52 [1] . ‐ Formation of Copper Silyl and Stannyl Complexes by Reaction of [Ph 3 PCuH] 6 with HER 3 (E = Si, Sn) [Ph 3 PCuH] 6 was used as a source for the Ph 3 PCu fragment to prepare copper stannyl and silyl complexes. Reaction of [Ph 3 PCuH] 6 with HSnPh 3 , HSiPh 3 or HSiClPh 2 , respectively, and two equivalents of PPh 3 yielded the complexes (Ph 3 P) 3 CuER 3 (ER 3 = SnPh 3 , SiPh 3 , SiClPh 2 ).

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