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Phosphite‐Derivatized Ruthenium‐Carbohydrate Complexes in the Catalytic Hydration of Nitriles. Short Communication
Author(s) -
Ashraf Shaheen M.,
Berger Isabella,
Nazarov Alexey A.,
Hartinger Christian G.,
Koroteev Mikhail P.,
Nifant'ev Eduard E.,
Keppler Bernhard K.
Publication year - 2008
Publication title -
chemistry and biodiversity
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.427
H-Index - 70
eISSN - 1612-1880
pISSN - 1612-1872
DOI - 10.1002/cbdv.200890151
Subject(s) - ruthenium , chemistry , catalysis , ligand (biochemistry) , combinatorial chemistry , metal , carbohydrate , nitrile , organic chemistry , receptor , biochemistry
The synthesis of metal complexes with bioligands is one option to introduce chirally defined ligands to catalysts. Herein, the hydration of nitriles to the corresponding carboxamides by use of ruthenium(II) complexes is described, which were obtained by attaching derivatives of the 3,5,6‐bicyclophosphite‐ α ‐ D ‐glucofuranoside ligand.