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Selective binding of Ni 2+ and Cu 2+ metal ions with naphthazarin esters isolated from Arnebia euchroma
Author(s) -
Sharma Nidhi,
Gulati Ashu
Publication year - 2020
Publication title -
biotechnology progress
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.572
H-Index - 129
eISSN - 1520-6033
pISSN - 8756-7938
DOI - 10.1002/btpr.2985
Subject(s) - metal ions in aqueous solution , metal , chemistry , ion , absorption (acoustics) , chelation , absorption spectroscopy , selectivity , nuclear chemistry , inorganic chemistry , photochemistry , materials science , organic chemistry , physics , quantum mechanics , composite material , catalysis
Abstract Naphthazarin esters (C1–C4) isolated from the roots of Arnebia euchroma are found as skilled dual chemosensors for Ni 2+ and Cu 2+ among Pb 2+ , Na 2+ , K 2+ , Hg 2+ , Mg 2+ , and Ca 2+ metal ions. C1–C4 esters exhibited a red shift of 54 nm with Ni 2+ and 30 nm with Cu 2+ metal ions in absorption. There is a formation of red‐shifted bands between 517 and 613 nm in the absorption spectrum of C1–C4 sensors on binding with Ni 2+ and Cu 2+ ions. The addition of Ni 2+ and Cu 2+ ions to sensors C1–C4 stimulates a remarkable color change from reddish pink to purple and light blue, respectively. These color changes can be identified with the naked eye. The significant downfield shifts of CO and OH peaks in nuclear magnetic resonance (NMR) spectrum confirm the chelation as binding mechanism. With ultraviolet–visble and NMR studies, it is found that C1–C4 esters possessed notable selectivity and sensitivity toward Ni 2+ and Cu 2+ over other metal ions.