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Fast atom bombardment mass spectrometry of elymoclavine glycosides
Author(s) -
Havliček Vladimír,
Flieger Miroslav,
Křen Vladimír,
Ryska Miroslav
Publication year - 1994
Publication title -
biological mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 1052-9306
DOI - 10.1002/bms.1200230203
Subject(s) - fast atom bombardment , mass spectrometry , chemistry , glycoside , ion , atom (system on chip) , high resolution , analytical chemistry (journal) , computational chemistry , stereochemistry , organic chemistry , chromatography , remote sensing , computer science , embedded system , geology
A series of nine naturally occurring and/or semi‐synthetic elymoclavine mono‐ and oligoglycosides containing various sugar units was investigated by fast atom bombardment, high‐resolution measurements and linked scans. The fragmentations of the [M + H] + and [M + Na] + ions are described and their different contributions to the structure elucidation are discussed.