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Fast atom bombardment mass spectrometry of nucleosides and nucleotides
Author(s) -
Eagles J.,
Javanaud C.,
Self R.
Publication year - 1984
Publication title -
biomedical mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0306-042X
DOI - 10.1002/bms.1200110108
Subject(s) - fast atom bombardment , protonation , deprotonation , field desorption , chemistry , thermospray , mass spectrometry , mass spectrum , nucleotide , ion , spectral line , ionization , atom (system on chip) , computational chemistry , organic chemistry , chromatography , tandem mass spectrometry , biochemistry , physics , astronomy , gene , computer science , embedded system , selected reaction monitoring
The positive and negative fast atom bombardment spectra of two nucleosides, 10 mononucleotides, two derivatized mononucleotides and 11 dinucleoside monophosphates have been recorded. Molecular ions (protonated or deprotonated) and some structurally significant fragments, sometimes involving cationization, were obtained. The spectra were compared with field desorption and thermospray ionization spectra whenever possible.