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Mass spectroscopy of natural products. XVI—Mass spectroscopic studies of thiazinylergolines
Author(s) -
Schmidt J.,
Seifert K.,
Härtling S.,
Johne S.,
Veith H. J.
Publication year - 1982
Publication title -
biomedical mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0306-042X
DOI - 10.1002/bms.1200090408
Subject(s) - fragmentation (computing) , mass spectrometry , chemistry , substituent , collision induced dissociation , dissociation (chemistry) , mass spectrum , alkyl , spectroscopy , computational chemistry , medicinal chemistry , organic chemistry , tandem mass spectrometry , chromatography , physics , computer science , quantum mechanics , operating system
The fragmentation behaviour of D‐6(6‐alkyl‐4 H ‐1,3‐thiazin‐4‐on‐2‐yl)‐8‐methoxycarbonylergolines‐I is described. Using collision induced dissociation (CID) mass spectrometry it could be established that the structure of the heterocyclic substituent at N‐6 of the ergoline is retained during the fragmentation.