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Aporphines: 25—Trimethylsilyl derivatives of N ‐methyl and N ‐propyl aporphines: Gas chromatographic and mass spectrometric properties
Author(s) -
Green J. F.,
Evans J. V.,
Neumeyer J. L.,
Vouros Paul
Publication year - 1979
Publication title -
biomedical mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0306-042X
DOI - 10.1002/bms.1200060704
Subject(s) - trimethylsilyl , chemistry , chromatography , organic chemistry
A series of synthetic, semisynthetic and naturally occurring aporphine alkaloids were converted to the O ‐trimethylsilyl derivatives, and analyzed by gas chromatography mass spectrometry. A discussion of discussion of structurally informative fragment ions along with gas chromatographic data is presented. Their applicability to the analysis of biological metabolites of apomorphine, a CNS active structural analog of dopamine, is discussed.