[OH] −  negative chemical ionization mass spectrometry. Reactions of [OH] −  with methadone,  l ‐α‐acetylmethadol and their metabolites | Zendy

Smit Andre L. C. | Zendy; Field F. H. | Zendy

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[OH] − negative chemical ionization mass spectrometry. Reactions of [OH] − with methadone, l ‐α‐acetylmethadol and their metabolites

Author(s) -

Smit Andre L. C.,

Field F. H.

Publication year - 1978

Publication title -

biomedical mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0306-042X

DOI - 10.1002/bms.1200051004

Subject(s) - chemical ionization , fragmentation (computing) , chemistry , ionization , methadone , mass spectrometry , mass spectrum , electron ionization , atmospheric pressure chemical ionization , analytical chemistry (journal) , chromatography , ion , organic chemistry , pharmacology , medicine , computer science , operating system

The [OH] − chemical ionization spectra of methadone and three metabolites and of l ‐α‐methadol and six metabolites are presented. The spectra are simple, but the methadol compounds exhibit much fragmentation. The ionization sensitivity is somewhat greater than that in CH 4 positive chemical ionization.

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