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Mass spectrometry of N ‐acylated daunorubicin derivatives
Author(s) -
Roller P. P.,
Sutphin M.,
Aszalos A. A.
Publication year - 1976
Publication title -
biomedical mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0306-042X
DOI - 10.1002/bms.1200030405
Subject(s) - daunorubicin , fragmentation (computing) , chemistry , mass spectrometry , mass spectrum , chromatography , leukemia , medicine , biology , ecology
The mass spectra of peracetylated daunorubicin, N ‐octanoyl‐, N ‐dodecanoyl‐ and N ‐( N '‐dodecanoylglycyl)daunorubicin, and perdeuteroacetylated N ‐dodecanoyldaunorubicin were analyzed. Major fragmentation pathways were suggested and ion compositions were determined by high resolution measurements.