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Reversed‐phase high‐performance liquid chromatography of fullerenes with tetrahydrofuran‐water as a mobile phase and sensitive ultraviolet or electrochemical detection
Author(s) -
Santa Tomofumi,
Koga Daisuke,
Imai Kazuhiro
Publication year - 1995
Publication title -
biomedical chromatography
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.4
H-Index - 65
eISSN - 1099-0801
pISSN - 0269-3879
DOI - 10.1002/bmc.1130090212
Subject(s) - chemistry , tetrahydrofuran , chromatography , ultraviolet , phase (matter) , fullerene , high performance liquid chromatography , electrochemistry , organic chemistry , electrode , optoelectronics , solvent , physics
Fullerenes (C 60 and C 70 ) were separated on a reversed‐phase high‐performance liquid chromatography column with a mobile phase of tetrahydrofuran‐water (70:30, v/v) and detected with ultraviolet or electrochemical detection. A baseline resolution of C 60 and C 70 was achieved with a capacity factor values of 7.6 and 10.8 respectively and a resolution of 3.7. The detection limit for C 60 was 0.1 pmol on column and was nearly the same for both detection methods.