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Zinc‐based Metal Organic Framework Derived From Anthracene and BODIPY Chromophores: Synthesis and Photophysical Properties
Author(s) -
Gupta Gajendra,
Kim Miyeon,
Lee Junseong,
Lee Chang Yeon
Publication year - 2021
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
ISSN - 1229-5949
DOI - 10.1002/bkcs.12269
Subject(s) - bodipy , chromophore , zinc , photochemistry , chemistry , anthracene , fluorescence , luminescence , ligand (biochemistry) , metal organic framework , metal , photocatalysis , materials science , organic chemistry , catalysis , adsorption , receptor , biochemistry , physics , optoelectronics , quantum mechanics
Luminescent metal–organic frameworks (MOFs) have emerged as interesting materials due to their excellent photophysical and photochemical properties. Herein, we report the synthesis of a Zn‐based MOF AnDBP MOF derived from anthracenedicarboxylic ligand and dipyridyl boron dipyrromethene (BODIPY) chromophore. The single‐crystal structure of AnDBP MOF showed a noninterpenetrated network structure with zinc metal binding the ligands in an octahedral fashion. The AnBDP MOF showed efficient energy transfer between the linkers and also displayed excellent photocatalytic properties.