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Pd‐Catalyzed Negishi Cross‐Coupling of Vinyl Bromides with Diborylmethylzinc Chloride
Author(s) -
Kim Minjae,
Lee Jun Hee,
Cho Seung Hwan
Publication year - 2021
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
ISSN - 1229-5949
DOI - 10.1002/bkcs.12212
Subject(s) - negishi coupling , allylic rearrangement , scope (computer science) , chemistry , catalysis , vinyl chloride , chloride , combinatorial chemistry , organic chemistry , computer science , programming language , polymer , copolymer
We have developed Pd‐catalyzed Negishi cross‐coupling of diborylmethylzinc chloride with vinyl bromides. The reaction shows a broad scope and an array of α‐boryl‐substituted allylic boronate esters are obtained in high efficiency.