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Enhanced Photothermal Heating from One‐dimensional Assemblies of Au Nanoparticles Encapsulated by TiO 2 Shell
Author(s) -
Biutty Merreta Noorenza,
Zakia Maulida,
Yoo Seong Il
Publication year - 2020
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
ISSN - 1229-5949
DOI - 10.1002/bkcs.12106
Subject(s) - nanoparticle , surface plasmon resonance , photothermal therapy , plasmon , materials science , nanotechnology , photothermal effect , chemical engineering , shell (structure) , chemistry , optoelectronics , composite material , engineering
One‐dimensional assemblies of metal nanoparticles (NPs) may represent an interesting plasmonic superstructure, in which localized surface plasmon resonance of individual NPs can be coupled to modify the strength and wavelength of extinction of metal NPs. In this study, we explored a simple method to assemble Au NPs into a linear chain by utilizing a low‐dielectric solvent and salts. The aggregation states of Au NPs were engineered by the concentration of salts, which resulted in isolated and linearly assembled Au NPs. In addition, the TiO 2 shell, as a stabilizing layer, was synthesized on the surface of the isolated and assembled Au NPs by a slow hydrolysis process. Because the linearly assembled Au NPs with a TiO 2 shell had a broad extinction spectrum by plasmon hybridization, they could absorb more photons under simulated solar irradiation. As a result, the linearly assembled Au NPs with a TiO 2 shell exhibited an enhanced photothermal effect, compared with the isolated ones.